The dataset contains 5G positioning measurements simulated using a MATLAB raytracer tool in realistic environments (outdoors and indoors).Outdoor scenarios include static and dynamic users in the urban area of Città Studi, Milan, Italy, near the Politecnico di Milano - Campus Leonardo.The indoor context is reconstructed using a LiDAR acquisition in the MADE Competence Center I4.0 located in Politecnico di Milano - Campus Durandò, Bovisa, Milan, Italy.The datasets include:Base station (BS) coordinates;User equipment (UE) coordinates;Raw measurements (TDOA/RTT/AOA/AOD).Each measurement will be marked with an integer timestamp (1,...,1000) and a boolean value (0/1) to indicate if the BS is in line of sight (LOS) or not (NLOS).The simulations comprehend a plethora of experiments. For instance, a comparison between the different numerologies (0, 1, 2, 3), methods (DL-TDOA, multi-RTT, UL-AOA, DL-AOD), and BS array (4x4, 8x8, 16x16).